Some words are possible and some are not, even those that use sounds that we have! Why?
Such a word (ndela) violates the phonotactic constraints of english.
Phonotactic constraints: language-specific set of rules governing what combinations of sounds are licit.
Language-specific: “ndela” sounds right to Swahili speakers; “skrs” is right in Czech.
Positional restrictions:
Sounds that simply aren’t part of the inventory.
Restrictions cannot appear adjacently.
If a word that violates phonotactics it might be “repaired” to adhere to constraints.
There are usually no clear boundaries between syllables on a spectrogram: they are a mental construct. They are still part of phonotactics, since native speakers have a robust intuition about them.
Phonology: Mental reality of sounds; the system of the sounds of a language. Uses categorical variables.
Phonetics: The physical reality of sounds, using continuous variables like time and fundamental frequency.